Iodotrifluoroethylene

Iodotrifluoroethylene
Names
Preferred IUPAC name
1,1,2-Trifluoro-2-iodoethene
Other names
1,1,2-Trifluoro-2-iodoethylene, trifluoroiodoethylene, iodotrifluoroethylene
Identifiers
3D model (JSmol)
ChemSpider
ECHA InfoCard 100.006.028
EC Number
  • 206-629-9
UNII
  • InChI=1S/C2F3I/c3-1(4)2(5)6 Y
    Key: PZVZTKFRZJMHEM-UHFFFAOYSA-N Y
  • InChI=1/C2F3I/c3-1(4)2(5)6
  • F/C(F)=C(\F)I
Properties
C2F3I
Molar mass 207.92 g/mol
Density 2.284 g/cm3
Boiling point 30 °C (86 °F; 303 K)
Hazards
Occupational safety and health (OHS/OSH):
Main hazards
 Irritant (Xi)
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Y verify (what is YN ?)

Iodotrifluoroethylene is the organofluorine compound with the formula C
2F
3I. It is a volatile colorless liquid.

Preparation and reactions

It is prepared by iodination of trifluorovinyl lithium.

Iodotrifluoroethylene reacts with cadmium metal to give CdC2F3(I).


It reacts with nitric oxide under UV light, producing a nitroso compound, with iodine as a byproduct:

2 C
2F
3I + 2 NO → 2 C
2F
3NO + I
2

References

  1. ^ Burdon, James; Coe, Paul L.; Haslock, Iain B.; Powell, Richard L. (1996). "The hydrofluorocarbon 1,1,1,2-tetrafluoroethane (HFC-134a) as a ready source of trifluorovinyllithium". Chemical Communications: 49. doi:10.1039/CC9960000049.
  2. ^ Burton, Donald J.; Yang, Zhen-Yu; Morken, Peter A. (1994). "Fluorinated organometallics: Vinyl, Alkynyl, Allyl, Benzyl, Propargyl and Aryl". Tetrahedron. 50 (10): 2993–3063. doi:10.1016/S0040-4020(01)81105-4.
  3. ^ Griffin, C. E.; Haszeldine, R. N . (1960). "Perfluoroalkyl derivatives of nitrogen. Part VIII. Trifluoronitrosoethylene and its polymers". Journal of the Chemical Society (Resumed): 1398–1406. doi:10.1039/JR9600001398.


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