Trichloronitrosomethane

Trichloronitrosomethane
Names
Other names
TL-358
Identifiers
3D model (JSmol)
ChemSpider
  • InChI=1S/CCl3NO/c2-1(3,4)5-6
    Key: WXWITNRAXGTELB-UHFFFAOYSA-N
  • C(N=O)(Cl)(Cl)Cl
Properties
CCl3NO
Molar mass 148.37 g·mol−1
Appearance Deep blue liquid
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).

Trichloronitrosomethane is a chlorinated nitrosoalkane. It is a deep blue liquid with powerful lachrymatory effects.

Synthesis

Trichloronitrosomethane can be produced with following methods:

Chemistry

Trichloronitrosomethane is an unstable substance. It slowly decomposes into nitrosyl chloride, nitrogen oxides, and chloropicrin over time.

Trichloronitrosomethane can be reduced to phosgene oxime by hydrogen sulfide.

See also

References

  1. ^ a b c d Sartori, Mario (1939). The War Gases. New York: D. Von Nostrand. pp. 164–165.
  2. ^ Sutcliffe, H. (September 1965). "The Synthesis of Trichloronitrosomethane". The Journal of Organic Chemistry. 30 (9): 3221–3222. doi:10.1021/jo01020a516.