User talk:Qflib

Glad to have your input. My motto is "I'm happy to help," so ask me anything! I do make mistakes, and am happy to correct them and to discuss any and all issues. If you are responding to a post I left on your talk page, please do so there to keep the conversation intact. If you are responding to an edit I made to an article, please **don't** post here - instead, leave a comment on the article talk page.

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Questions to you on the perfect gas talk page

Hello. I don't know it is ok to write here. Please delete my message if it is not ok.

I just wanted to bring to your attention that I have replied to one of your comments on the talk page of the perfect gas article with a few questions.

I have replied using @Qflib, but since I am not sure that it actually alerts you, I thought I might write to you here as well to make sure that you get the information and have the chance to look at the questions.

Thank you. 2A01:E0A:179:4500:B9E3:4442:1AD5:F6D3 (talk) 12:47, 28 November 2024 (UTC)[reply]

Definitely okay to write to me here - actually this is a better place to ask me questions directly than on the article talk page, which really should be dedicated to conversations about specific ways to make the article better. But it's all good. Qflib (talk) 20:07, 28 November 2024 (UTC)[reply]
Perfect. Thank you very much for your replies, both here and on the talk page. 2A01:E0A:179:4500:B9E3:4442:1AD5:F6D3 (talk) 17:21, 29 November 2024 (UTC)[reply]

---

Hello again.

As I continued to read and reflect on those issues, new questions came to me, and I was wondering if you could answer them (and maybe they could inspire complementing points to the article?):

  • Regarding the dependence of Cp and CV on the temperature in the case of the ideal gas, you wrote that "temperature dependence is well known to arise from intramolecular forces causing highly quantized molecular vibrations which may or may not be thermally accessible at a given T". Shall it be understood that the temperature dependence comes not merely from the existence of internal degrees of freedom in a molecule but from the fact that the "number" (or "amount") of degrees of freedom varies with temperature? In other words, a gas of "classical" multi-atomic molecular entities would not give temperature-dependent Cp or CV because its "number" (or "amount") of degrees of freedom would always stay identical, whatever the temperature?
  • Incidentally, if the internal structures of the molecules which compose the gas affect the temperature dependence of Cp or CV in the case of an ideal (or semi-perfect) gas, does it imply that Cp and CV should also then be considered in general dependent not only on p or T, but also on the composition of the gas (which would not be the cas for a perfect gas)?

Thank you for your insight. — Preceding unsigned comment added by 91.165.229.20 (talk) 14:29, 15 December 2024 (UTC)[reply]

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